When I was playing with smooth like sidewalk surplus rifles, I used CR10 to 'mine' the copper. Works great and I still consider this the best commercial solvent for heavy work.
I have since moved on to something far more economical that also works, arguably, better.
Janitorial Ammonia Solvent. This is as concentrated as you can get without a license. USE OUTDOORS ONLY. EVEN VENTILATION IN A ROOM IS NOT ENOUGH.
Wipe it in, wipe out the copper. No waiting, no mucking about, just gets the job done FAST. I got mine at ZEP supply.
The time it takes to change a patch is all that it needs to sit. DIRT cheap at around $20 a gallon which will give you and a bunch of your friends enough solvent to clean for a decade. You use very little as it is so effective.
You never let it sit or dry so any fears of damage to steel is unwarranted (I have never seen ammonia damage steel either and I have tried). You will need a bit of oil after as it cleans to bare metal.
One surprising effect is that it can cut through some really cruded in powder fouling too.
I use it in my match barrels and I just don't see any powder caking in the throat. I have done autopsy on two 6.5's and there is simply no fouling in the throat area at all.
Of course, you can mix it with an oil or water to dilute. You end up with a strong commercial solvent
Another option is JB reg. or Borebrite. This will manually cut out the copper. Works very well.
Jerry