You have made a very interesting observation.
The typical knee jerk response to the question of what is more powerful a 308 win or 3006 - most guys would simply answer 3006. But it's a loaded question, because it also depends heavily on the weight and ballistic cooeficient of the bullet and the distance of a particular shot.
Given the 155 SMK a 308 winchester will outperform a 3006 with 180 grain Sierra Pro Hunter bullet at 600 yards all day long. Reverse the bullets and the opposite will be true.
In addition, in relation to powder capacity there is the point of diminishing returns. As the powder charge is increased the powder burn rate must be decreased to stay within pressure limits. So the more powder in the case, the less efficiently it is used.
This also applies to bullet weight. As the bullet weight is increased, the powder burn rate must be decreased. So heavy bullet and large case capacity is inefficient for 2 reasons. For that reason you will often find smaller rounds that perform similarily to large overbore rounds.
In the case of 3006, typically it's offered with heavier 180 to 200 grain bullets which often have no better BC than a 155 grain SMK, especially in hunting bullets.
As the distance is increased, the payoff of having a good BC really pays off because it does not slow down at the same rate as a low BC typical hunting type bullet.
Beyond all of the above, confusion is deliberately created by marketing literature of the companies who produce this stuff, simply as a means of selling it to guys who dont know any better or even care. Some guys just like Camaros and other guys like Baracudas. Who cares why?
In the end, you are very correct in the similarity between most of them is hardly worth arguing about, and I cant begin to imagine the number of teeth that have been knocked out at hunting camps arguing over the difference.
In terms of round selection, I personnaly like the formula that seems to hold true for the most succesful long range target rounds, as follows. Using the heaviest bullet available in each caliber, the case powder charge should be about 1/3 of the bullet weight. Pick the weight of bullet you want to shoot, .224= 80 grain, 6mm 115 grain, 6.5mm= 142 grain, 7mm =180 grain, 308 =240 grain. Then go to the reloading manual and find a case that holds about 1/3 of the bullet weight in powder charge...
.224= 27 grains powder, 6mm = 38 grains powder, 6.5 mm = 47 grains powder, 7mm = 60 grains powder, 308 = 80 grains powder. In terms of ballistics you cannot go wrong if you follow this formula.
If you dont care about long range and just want to pick a round based on availability, forget this tech stuff and get whatever you can readily find. They all kill on impact if you place it right.