Check your headspace, 'tis all. That, and the stated pressures of the ammunition in question. Generally, should be okay, but let's hear from the others!
Pretty Much. They are NOT the same, nor should they be considered interchangeable, but that does not mean it can't be done with a little homework. NATO chambers are a smidge longer than civilian .308 win. This means the cases often stretch during obturation. No big deal to a durable one-time-use NATO brass, and a tough mil-spec barrel. In a civilian .308 win however, that brass is often thinner, lighter, and more prone to failure in the longer chamber.
In your old surplus rifle, as long as you are not looking to run custom or overly hot loads, and you have a decent unmodified rifle, there is likley no big safety issue. If you have an older pre-WWII rifle or a conversion, you could be looking at safety issues. There is a greater chance of the civvy win. ammo developing higher pressures, and therefore a greater chance of a double failure (case, chamber/bolt).
In my days with the old FN C1's (FAL) and even older surplus ammo, I have seen many ruptured cases. Sometimes surprising, and often frustrating, the rifles held up just fine. They were designed too.
My recommendations (take it FWIW):
1. Thoroughly inspect and measure the chamber of your new surplus rifle to ensure it is not too far out of spec. Mass production by the lowest bidder can create significant variances. If you aren't an expert, pay a good smith to do it.
2. Don't use civvy ammo in pre-WWII converted rifles like the old mausers. You are asking for a messy failure.
3. Don't reload the brass used in a surplus rifle. Some experts may with thorough resizing. Read: EXPERTS!
4. EXPECT FAILURES! They will happen on occasion, so wear shooting/safety glasses. A good recommendation with any older rifle anyway.
5.
Don't ever try to "jam" surplus NATO ammo in a civvy rifle chamber. If it is stretched, the bolt may not lock, and you will get hurt!
You pays your money, you takes your chances...
