As an up and coming barrel maker I can tell you there most certainly is a difference in the metallurgy of the two barrel steels........stainless steel barrel blanks are made from 416 ss stress relieved and annealed, the CrM blanks I use are 4150 and are stress relieved and annealed. These are also the 2 types that Ron Smith uses.
The SS blanks are no more difficult to machine than the CrM blanks but one must use the correct cutting oil for each. There are some oils that do double duty quite well but I prefer the specific oils per type of steel.
416 SS RESISTS corrosion much better than Crm steels do, but will stain.....I have never seen a SS barrel pit though. The biggest problem with not maintaining SS rifles is that not all parts of a barreled action are stainless. Rem 700 bolts for example, are 4340 and will rust. This is done as SS on SS will gall very quickly without some lubrication, rendering the rifle useless, but of course no one here would ever run their locking lugs dry.............other parts like extractors, firing pins, and springs are usually not SS so one must still maintain them somewhat.
Most 416 SS barrels will still hold a magnet as the primary material is still steel and the other materials which create the stainless properties are a minor part in the make up of the barrel steel. All my barrels that I use are now SS and I wonder why anyone would use anything else unless building a custom rifle and want a super deep and lustrous blue job for appearance sake. If one doesn't like the white appearance one can always Teflon or cerracote it any color he chooses.
I have used SS Rem 700s in some of the most inhospitable climates in the world, like the Congo, and my barreled actions show no signs of discoloration but I daily had to WD40 (no wait, they took my WD40 away at the airport, along with my duct tape. Terrorist devices you know, I used some gun oil left in camp by a previous hunter.) to protect my bolt and scope mounts. The heat and humidity will really raise hell with CrM steel parts.
The benchrest crowd have also determined that 416 SS resists throat erosion slightly better than CrM steels do so barrel life is extended somewhat.
And this is what rain looks like in the Congo, and its 28 degrees..............I was told this is about 4"/hr, the heaviest rainfall I have ever seen !!! This was pretty much the scenario every mid afternoon.
![]()
Of course there is a difference in metallurgy. I was referring to the maintenance to the end user. One takes a bit more regular oiling than the other.