Short answer: realistically, you can only expect 12/14, 14 and 32 gauge to be classed as antique here.
Long answer: if yours does not chamber any of the gauges listed by honourable tiriaq, and is not stamped in any of those, it's antique, because the olden days shotguns were sometimes made to odd gauges, such as 15, 18 and others. It's very unlikely you will come across those, but not impossible.
Note: it must not chamber due to diameter, not length - because 12 ga with 2" chamber, which does not chamber 12ga 2 3/4 hulls is not antique.
There's 24ga, but it's very rare. More rare than 14ga.