Those big primers are always corrosive and mercuric, both. NO Z in the headstamp will always be Cordite. The big primers are always a dead giveaway for Cordite rounds.
The Z indicated loading with a cut extruded powder which was a Canadian version of Nobel Neonite. For handloading purposes, it was in much the same ballpark as IMR-4895.
The Defence Industries plant ( DI headstamp) was a Government plant but they were leaning heavily on critical staff from the commercial Dominion Cartridge Company. Primers used are .210" Boxer type and they are NONcorrosive and NONmercuric. The DI brass is some of the finest handloading brass ever produced for the .303 cartridge. DI made about 2 Billion rounds of this ammo, so there still are bits and pieces of it to be found in circulation.