There is a gap between the boltface and the breechface of the barrel.
This is the space where the rim of the cartridge sits.
There are tolerances for the thickness of the rim, and the size of this gap.
Ideally, the gap between the boltface and the breechface should be .064" to .068". The military would allow a rifle with a gap of less than .074" to remain in service.
The rim is nominally about .060 thick.
Headspace is tested with gauges, Go (.064), No Go (.068), and Field (.074).
Using gauges is not exactly the same as actually measuring the gap between the two faces. This would produce an exact measurement.
Headspace gauges test for a Pass - Fail situation.
Easiest, fastest way to check your rifle is with gauges. Most any gunsmith in Canada is going to have .303 gauges.
You can get a rather accurate measurement of the gap between the faces using an unfired cartridge case, shimstock and a good micrometer. Once this measurement is established, you will have a pretty good idea what the situation is with respect to headspace in the rifle.