I have a reference to a James Harper, 1850 - 1865, of 85 Weyman Street, London and who is listed as making percussion pepperboxes and flat bar hammer percussion revolvers. Your gun appears to have Birmingham proofs, but maybe it was made by a relative. The time period I am guessing is between 1840 and 1860 or so. You should try to clean the rust out of the barrel and hone them a bit. If the pitting is not too deep, you might be able to shoot it. Your muzzles look fairly thin and I would think you would want them to be at least .020" thick. I would suggest taking it to a gunsmith who is knowledgeable of black powder and antiques and get an opinion from him. If the smith is a modern gun only person, his answer will be an automatic no it will blow up. You will have to replace the nipples and the threads are probably 1/4 x26 which is british national fine as well as a metric pitch of 1 mm (I think) Don't assume that the diameter is going to be an automatic .250 and I would suspect the threads would need to be chased out to fresh metal and an oversize nipple thread used
cheers mooncoon