Hasbin, I do not know the answer to your question, but I am stuck at home with a miserable virus and have nothing better to do, so I will speculate. Besides, anyone who shoots a Darne deserves some sort of an answer.
1) You are correct about the loose/snug fit of the adapter, it should extract just like a shotshell. You then use a small rod to poke the fired brass out of the adapter.
2) A 2 3/4" shotshell is only 2 3/4 inches long after it has been fired (or before it is crimped in the loading process). This will be a problem if the adapter is made to fully occupy a 2 3/4" chamber, it will not physically fit in a 2 1/2" chamber as it will run into the forcing cone.
3) A .32 ACP firing a 71 grain bullet at 1000 fps (pretty much max) will generate 0.35 pound-seconds of recoil energy. Assuming you are using 1 ounce of shot at 1100 fps for your 2 1/2" skeet load you will be generating about 2.49 pound-seconds with the 12 gauge shell. The surface area of the rear of the .32 ACP should be 0.10 sq. inches, the surface area of the 12 gauge shell close to 0.6165 sq. inches. Convert both to pound-seconds per square inch to compare and you get 3.5 pound-seconds per square inch for the .32 ACP, and 4.04 lb.-sec. per sq. in. for the 12 gauge. In my estimation you are not in any danger of damaging the sliding breech by shooting .32 ACP.
NOTE: I have never done this before, it is best that you re-do the logic and math for yourself !!!
Another question is that of accuracy, what good would it be if you couldn't hit anything? While 12 gauge chamber size standards are published, actual measurements of production guns can vary a bit. I think that an "off the shelf" adapter might have more "play" than you would be comfortable with (even if you could find one to fit the 2 1/2 chamber).
One answer might be to find a 4 or 5 inch long, 1 inch diameter barrel blank, take a cerrosafe casting of the Darne's chamber and give both items to a machinist who is good with a lathe. A custom fit and head space would not be a problem. The barrel should be long enough to burn most of the powder within it. The crown should be de-burred, a tumbling bullet would surely wreck a shotgun barrel. Have the finished product reamed for a .32 ACP chamber and blue the thing (or use a stainless steel barrel blank). Of course, this is probably much more trouble than you were thinking of and probably more expensive too, but I bet it would work.
Thanks for providing an interesting mental exercise. If you get around to doing this (custom or off the shelf) please let us know how it works out.
Sharptail