There is a SAAMI video that shows that smokeless ammo that explodes due to fire is not a danger to anyone unless it is confined (like in a barrel). Otherwise the pressure never builds up enough to be dangerous.
I am a firefighter and fire instructor. I'm putting the finishing touches on a seminar dealing with powder and ammunition in fire situations. I have the SAMMI videos as well as a video about powder from Natural Resources Canada. The NRCan video and accompanying report lead me to beleive that SAMMI used questionable science in their tests. SAMMI did all their powder tests outdoors whereas NRCan burnt powder in a 12 X 12 room. A room of that size will in fact act as like a container when 8lbs of powder burn in it. The overpressure was enough to raise the roof of the test building which was built to NBC standards.
My take is that ammunition is no big deal and 1 lb containers of powder are not bad. 8 lb containers scare me now.