Possibly because of light neck tension, the bullet moves forward before a lot of pressure is generated and some unburnt powder leaks past back around the neck before it seals.
Another factor might be that the cases have been reloaded a number of times and the necks have been work hardened, meaning that they will need a slightly higher pressure in the case to seal. Again, this might let a bit of unburnt powder past before the neck seals. Solution would be to anneal the case necks.