THe .303 rim is close in diameter to the head of the bolt. As soon as the bolt opens, the extractor pushes the rim sideways, and it will make contact with the left wall of the receiver. The left wall of the receiver is relieved progressively deeper toward the rear, to allow the casehead to continue to move to the left, slightly off the boltface. As the extractor draws the case from the chamber, and as the bolt is opened, the case is dragging against the left wall of the receiver. This drag may be sufficient to cause the case to pivot around the ejector hook, and fall free from the receiver. The relief cut in the left wall of the receiver gets progressively deeper, until it reaches the ejector screw. Because of the relief cut, the ejector screw is able to make positive contact with the case rim, and positive ejection results. When the bolt is opened in a snappy manner, the case is positively ejected when it makes contact with the ejector screw. Note that the ejector screw is not threaded to its tip - this prevents the threads from being dammaged during the ejection cycle.
The smaller diameter of the 7.62 case requires a retrofitted ejector; the case is not forced far enough to the left for ejection to occur in the same way as .303. 5.56 conversions are even worse. If the bolt is flatfaced, the case won't even make it all the way out of the chamber before falling off the ejector.