I've got some of the latest Barnaul, the primers seem to be armour plated - I tried running some in a new G19 (like right out of the box, zero rounds) and had multiple misfires. Pretty frustrating, but if you mix it in with your regular stuff, you'll get some very good IA practise with it.
Re: steel case/bi-metal jacket, barrel steel is many times harder than the soft crap they use for ammo, odds are you won't shoot enough of it to wear out a barrel, and if you do, you've saved the cost of a new barrel by shooting that much cheap ammo. A new match barrel for an M&P costs less than $200, it won't take a volume shooter long to save enough to cover a replacement barrel.