OK, I'll bite although I'll probably regret it. It might be a boring read. My experience with the .458 is mostly from zero to 200 yards. I started with loads that match factory claimed ballistics with buffalo being the main reason. At the time I didn't have all that many buffalo to my name, split between the .375 and the .416 and wasn't overly convinced that the .416 was killing anything better than the .375. I had a buffalo cull coming up when a .458 that I had ordered long before showed up out of the blue. Naturally the new gun was going to go, even if the planned conversion to .458 Lott wasn't done and since I had a favored .375 H&H that was going too. I viewed that as a perfect opportunity to decide once and for all whether it was worth while to use the big guns. Long story shortened a bit, I shot 16 buffalo on that trip and was able to conclude that the .458 did hit a lot harder, and the buffalo travelled less distance and took less shots. Still with me?
Despite being in second place the .375 did work after a fashion and since it wasn't because it was bigger or heavier it was natural to think that the only thing it had going for it was that it was faster. I got ahold of some A2230 and managed to get 450 A-Frames up to 2350 fps which is into Lott country. Things were a little slower for awhile but I shot buffalo here and there with whatever was handy. There was a borrowed .450 NE (isn't that what the .458 Win was supposed to be the replacement for?) and 30 caliber stunts before I got to try my Lottish level loads on a charging unwounded cape buffalo in Mozambique. Couldn't complain about the way those were hitting and the buffalo didn't do much more than a summersault or two. The bullets must have agreed because it was obvious that the bullets at the higher velocity were expanding quite a bit more at the new higher speed.
After that there was some lesser game leading up to more buffalo culling. It would have been a shame to not take the opportunity to learn something so a bunch of different bullets went with me, and since my favored A2230 powder wasn't going to available on the other side of the ocean that lead to having some fast loads and some with normal velocities plus 4 different softs and a couple different solids. Danged if the faster loads didn't continue to kill faster, and in the same vein the closer shots also hit harder simply because the velocity at impact was higher. I hate jumping to conclusions, so besides my own 112 buffalo on that trip I finished/recovered 20 or so that the others had hit first. Seemed like the neighbourly thing to do and I'm nothing if not neighbourly. Speaks to my upbringin'.
So anyway, where were we? Oh yeah, so after 123 buffalo with the .458 plus incidental animals to get that to say 160, plus another 20 buffalo on the good neighbour policy I'm sitting with the opinion that an A-Frame going as fast as you can push it is a force to reckoned with. The catch; 'cause there's always catch is that the Win case is filled to crimp failing capacity with the only powder that could produce those results. Add to that that the only powder that could produce those results isn't available anywhere its fun to hunt with a .458. Could it be that the .458 Lott guys were right the whole time? Just to build on that idea, there was no particular reason to stop at rod-rodded Win speeds with my new Lott chamber and the saga continues.
That's where my opinion comes from. Someone might be able to convince me otherwise, but it'll take some doing.