Tin canister? How long since they've made those? I'm relatively new to this but its all plastic these days...?
That means you missed paper canisters, with metal, rolled onto the top and bottom, with metal pop off tops? Those went the way of the willow appx 30 years ago.
Tins were still available up to 20 years ago and all through the combination carton days.
8 pound kegs were either paper board or painted steel.
25+ pound containers were usually heavy pressed paper. Some had large plastic bags inside of them, some didn't.
As long as it passes the smell test and isn't clumping, I would load it up and use it.
I have some IMR4064 in metal tins that have a bit of rust on the top. Doesn't seem to effect the performance at all. The metal inside the tin is still shiny.
I also had a bunch of surplus #44 powder, IMR3031 equivalent that started clumping as well as turning the metal tops of the cardboard canisters rusty. That stuff was actually corrosive to the bore when shot. Ruined a lovely barrel on a Mod 70 FWT, 257 Rob with it. It was an expensive lesson.
If you only have one tin, dump it. If you have a lot of it, open it all, and check it out. Blend it all together and test a few rounds against newer powder of the same description.
That being said, I've had new off the shelf powders in plastic containers with rust colored dust in them.