Yep that once shiney steel die has been electroplated, the cases furthest away from the die did not discolor. I trimmed the brass later today and noticed that discoloration is just on the very surface, inside is nice and brassy. The mix in the cleaner is 1 tbsp Lemishine 1 tsp detergent on a filled bath. I won't do this again for sure but thought it would be fun to post.
The Zinc in the brass (roughly 2/3 Cu and 1/3 Zn) together with the iron/carbon in the die "worked together" with the acid.
I'm no expert in this - but the pictures IMO show that Zinc from the brass could have wandered around towards the steel.
Hence, the more copper coloured cases showing signs be deprived off Zinc...
But maybe this method could be used to do some bluing on small parts ?