Black powder loads should be compressed slightly. As far as actual readings, there is a couple graphs posted here
http://www.canadiangunnutz.com/forum/showthread.php?t=249992&page=2 that show actual peak pressure readings for a few different loads, including a couple smokeless loads. If you look at the column titled 'peak', you'll see a list of three digit numbers. These numbers need to be multiplied by 100 to get psi. So, for example, the first number 193 = 19,300 psi.
As you look at the graphs, you will see that chamber pressures greater than 20,000 psi are quite normal for black powder 45-70 loads. You will also see why IMR SR4759 makes such a nice black powder substitute. From another article that I have, slower powders like IMR 4198, IMR 3031 and RL-7 give lower peak pressures than BP for the same velocity and bullet weights. You can also see from the graphs why Trail Boss, which is an extremely fast powder, is a bad idea in old BP guns, generating pressures well over 30,000 psi.
A general rule of thumb for estimating BP pressures for different BP cartridges is to look at a load table that had data for 2400 or IMR SR4759 and pick a load that gives the same velocity as BP loads, for the same weight cast bullet. The BP pressures will be pretty much identical to the 2400 or SR4759 pressures for that load.
I know that it is general knowledge that BP doesn't give much pressure, but that is simply not true on a couple different counts. First, is the tendency for BP to obturate the bullet, which requires a pretty hefty pressure spike. Second, are the actual chamber pressure measurements done and published by Sherman Bell. As Smellie pointed out, compressed BP does give higher pressures, and proper BP loading does require a certain amount of compression.