As Daniel posted, there is no benefit in accuracy for using 1 chamber over another these days because we fit the ammo to what is there and we have the tools to adjust our cases and bullets for a perfect fit.
Adding more info to the above:
From the base of the case to the base of the neck, these dimensions are specified by SAAMI AND all competition bodies. This is the DISPLACEMENT of the chamber and many competitors would love to tweak this if they could. Any chamber that is legal to be used as a 308win chamber will vary no more then a few thou here and there so there is likely more variation in the MAKING of the reamer then what is on a sheet of paper
The neck area (top of shoulder forward) only has to be sized large enough to allow the bullet to release properly under the conditions the rifle will be used. By the time the neck moves 1 thou during the firing process, that bullet is on the move. The rest of the expansion allows for an orderly release. More clearance will not hurt, except maybe allow for more neck splits. Too little WILL cause big problems in the form of pressure spikes.
"tight" or close tolerance chambers are only recommended when the rifle will not see a dirty environment and when the reloader will control the thickness of the case neck.
The final area that is played is the throat/leade. here the goal is to allow a particular class or type of bullet to be seated so that max capacity can be achieved vs other set up needs (mag or single feed, etc). The relative location of the ogive to the lands is really arbitrary and can be dealt with during the loading process.
Leade angles are also of little relevance as the actual difference in steel is so minute vs how this area will change as rds are fired - throats do not stay the same.
So a "custom" chamber really is about matching the ammo you want to shoot vs how the ammo will be fed. The accuracy is in the installation of that barrel, quality of the barrel, bedding of the action, ammo tuning of an accurate bullet - The chamber is merely the space that allows this to happen
Jerry