Well, this is just MY opinion on this, take it how you will...
If you are a benchrest target shooter, where accuracy rules all, YES, fire-forming new cases may get you the accuracy you wish. Fire-forming means that the cases you use are perfectly fitted to YOUR gun's chamber, and that chamber only. There is absolutey no way that the next chamber made with the same reamer that yours was made with will be identical in all respects.
Why, you ask??
The answer is simple: metal wears. The steel reamer that makes the chamber of your particular gun will wear off some of the metal used to bore the chamber (this is why tool edges dull and need sharpening) for YOUR gun, and the next chamber made will not be the exact same as yours. A tool & die maker could explain this better, I'm sure, but what it really means is that no two chambers, even those made by the same tool, will have the exact same dimensions.
Hunters say "who gives a damn" and they're right. Hunters care only that the rifle shoots to where the sights are, so they can kill the target animal with one shot. They don't care about a millimeter of difference at 100 meters.
Benchrest shooters care only about how close the holes in the target are together. They use special dial cailpers to measure the groups they shoot in the target. Hunters just don't need (although it's nice to have for confidence in your rifle) that kind of accuracy.
IMO, if you're reloading your ammo for hunting, fire-forming your ammo isn't worth the trouble. If you're working on a wildcat, or benchrest target shooting, then fire-forming your ammo may be the way to go for ultimate accuracy.
It really depends on you and what you want to rifle and ammo to do.
YMMV