If you can shoot both eyes open it helps. A few other tricks that can help is don't keep your eye closed and look through the scope for long periods. Take breaks, open it between shots. Also try not to really squeeze your eye shut, just close it enough so it is closed, but not tensed. I know some people really seem to force their eyes shut, which can really put a strain on the muscles.
Another thing i used to do while surveying and looking through lenses for much of the day is to switch eyes. If you hunt you never know when you will need to shoot left handed to clear an obstacle or if in a stand location set up for someone left handed, so take a few shots to practise your off hand once in a while to balance it out.
Beyond that, just try to relax as much as possible, the more you tense up and strain the harder it will be on you.