If one looks at the drawings, one should be able to clean up a 222 chamber with a 223 reamer, however it doesn't always work this way. Not all, but most will leave a small ring where the 222 shoulder was, welcome to factory SAAMI max chambers. Regarding someone saying one may have to do something with rails and feeding, I can only surmise that you have never worked on rifles chambered for either cartridge. They are as far as rails and feeding goes, identical cartridges. The slightly longer body and farther ahead shoulder of the 223 is completely irrelevant with all that is concerned with feeding the cartridge into the chamber. The 222, 223, and 222RM all use identical actions and magazines without exception and all can be changed from one to another with out any action work what so ever.
As stated many times above......the standard twist rates of the 222 cartridge do not lend them selves to being chambered out to 223 and using the longer heavier bullets now commonly used in ball ammo. It would be the ruination of a good barrel, IMHO.