Since you are reloading, I would pick a cartridge that has a good selection of high BC bullets to accommodate the long range requirement that you have. The common .25 cal bullets that are out there do not compare well with some of the heavier .224, .243, and 6.5mm bullets on the market when it comes to ballistic coefficient.
High BC aka VLD (very low drag) bullets are crucial when shooting longer distances because they minimize the effects of wind deflection and drag. Reduced drag allows the bullet to carry more energy farther which means you get a flatter trajectory.
As for hunting I would rule out the .224 cal to shoot deer with. I'm not sure what the laws are in your area but .224 cal might not be legal anyway. That leaves the 6mm(.243) and 6.5mm calibers. The most common cartridges for them are the .243 Winchester and the .260 Remington respectively. The cartridge that stands out between the two is the .243 Winchester simply because it has a better selection of rifles and components to choose from.
As far as cartridge accuracy is concerned, the accuracy will depend more on the load you work up, the rifle you choose, and what you do to improve the rifle. Granted some cartridges are inherently more accurate than others, I'm pretty sure with a little work a .303 British will shoot 1/2" groups given the right load and gun to shoot it out of.
Advantages of the .243 Winchester
-Easy to find a good rifle in this caliber (but so are the others you mentioned)
-Can get good quality brass (Lapua etc...)
-Bullets easily available with BC's of over .5 (a must for long range)
-Reasonable recoil when doing allot of shooting (targets, gophers, etc..)
-Can be loaded with lighter bullet's that can just about match the 22-250 in trajectory.
-Still large enough to use with confidence on deer out to 400 yards.
Given your requirements I think a .243win would be a good choose or perhaps a .260 Rem or even a 6mm Rem if you can find one, but if you are going to choose between the .223, 22-250 or a 25-06 I would stick with a 22-250 but be sure to get a gun with a 1-12 twist or less so you can have the option to shoot heavier (high BC) bullets for long range.
Well I tried to be more informative than opinionated but either way I hope this helps you make your decision.
Dave H