I made some great reloads last Fall which gave me consistent sub-MOA groups out of my old hunting rifle. I had used once-fired factory brass from Federal and Remington. Over the winter I ordered some Winchester brass because I heard such good comments, then resized, primed and reloaded. They gave me aweful results around 3-4" groups. It could be because I FL resized them the first time through, where as I neck resized the once-fired brass. However, I tested two batches last fall - one FL, one Neck - and I only saw about a 1/2"-3/4" difference in the groups. So I thought I should check the case capacity. Below you will see me scribbling:
Bear in mind, I only had the patience to measure a single case of RP and Win. When filled with water, the difference is only ~1.1 grains. After some math, I calculated that translates to 3.66 drops = .23 cubic cm. Using the Lee Volume Measure Density Chart that comes with the Lee Perfect Powder Measure, I looked at the volume of H4831 and I calculated that .23 CC would allow an extra 3.17 grains (+/- .86 gr). The .86 variance comes from allowing for 1 drop of water more or less between the cases when measuring.
Question 1) Do you see anything wrong with how I measured?
Question 2) How much difference would this small variance actually make? (i.e. Can I blame the capacity difference, or should I look at other factors?)

Bear in mind, I only had the patience to measure a single case of RP and Win. When filled with water, the difference is only ~1.1 grains. After some math, I calculated that translates to 3.66 drops = .23 cubic cm. Using the Lee Volume Measure Density Chart that comes with the Lee Perfect Powder Measure, I looked at the volume of H4831 and I calculated that .23 CC would allow an extra 3.17 grains (+/- .86 gr). The .86 variance comes from allowing for 1 drop of water more or less between the cases when measuring.
Question 1) Do you see anything wrong with how I measured?
Question 2) How much difference would this small variance actually make? (i.e. Can I blame the capacity difference, or should I look at other factors?)