Civilian brass sometimes (should I say most of the time) have very thin rims. This may cause a heaspace problem with a large chamber.
I measured Remchester brass rims as small as 0.054", while mill brass usually runs around 0.062" (0.058" to 0.064").
Try the "protruding primer method" to give you an idea of the headspace of your rifle. Always us spent primer, though.
This text comes from the "Textbook of Small Arms, 1929, War Office" pp 194/195;
Test No.4 for Cartridge Head Space
1. With Rimmed Cases. - This type of case is positioned in the chamber by its rim butting on the face of the breech, and in order to ensure easy closing of the breech the space between the face of the bolt (or its equivalent), when fully forward, and the face of the breech must not be less than the greatest thickens of rim likely to be encountered in any cartridge.
This space, known as cartridge head space, must, however, be limited, since if it is greater than the thickness of the rim, the case will be forced back onto the bolt face on firing, and that portion of it immediately in front of the rim will be thereby removed from the support of the walls of the chamber. If the extent of this unsupported portion is excessive the case may burst.
With the British Service cartridge, as issued, no case with a thickness of rim more than .064 inch, or less than .058 inch, is likely to be found, these being the high and low limits of the manufacturing tolerances. Gauges with rims .064 inch in thickness form the lower limit when testing cartridge head space. Actions which close freely over this gauge will take all service cartridges. The amount of tolerance beyond this depends on several factors, and experiments have proved that the setback or case movement should not exceed .02 inch, otherwise separations may occur.The maximum amount of cartridge head space allowable has been determined as .074 inch, and gauges of this dimension are used by armourers in carrying out this test. Even a cartridge with a rim thickness of .058 inch is then unlikely to receive insufficient support, as the set back is only .074 inch - .058 inch = .016 inch.