Here's a couple of 45/70 loads in the 24-28K range that I've used (in the 43 Mauser using 45/90 brass with aloxed 390 grain cast bullets, but will perform much the same in yours):
SR-4759 - 28.0 gr - 1500 fps (powder available from Stittsville)
H4198- 40.0 gr - 1700 fps (Higginsons - where else?)
I tried a variety of loads with RL-7 and did not like it in the 45/70, but it works well in the 303 Brit. Position sensitive and even if I tipped the gun up before each shot, I got wide velocity variations. I am leaning more and more towards slower powders and fuller cases, i.e. Varget. Uses more powder, but gives same velocity at lower pressures and is not posiiton sensitive. Still, I'm also playing with Higginson's surplus N-69 using Alliant 2400 loads and it is working ok, just the position sensitive thing again.