Unique is good powder in 455 webley. Does tend to be dirty in lighter loads but it still works even then. That said, I don't know of a better powder for these old low-pressure cartridges. The faster burning pistol powders like Bullseye & 700X also work well but also have a steeper pressure curve. Unique burning characteristics are not so abrupt and maybe closer to 3f black powder.
The Lee data has been heavily sanitized by their legal section, probably due to the age and condition of some 455 webley revolvers.
Occasionally you'll read advice to "work up a load" in these antique revolvers, and that can be misleading. Max pressure for the antique 455 webley revolvers is about 13K psi. There will be no pressure signs except possibly primer extrusions on sloppy firing pin channels at anything under 20K psi or more. Don't depend on fired brass to tell you when you're approaching maximum pressure. The first "pressure sign" could be your revolver coming apart. A chronograph is a good investment.
I load max 4.5gr Unique in the shorter MKII brass (Starline), and max 5gr Unique in the older MKI and Dominion brass with both 265gr HB and 220gr flat base and it's worked well.