With Quickload one of the first things it tells you to do is measure the case capacity of a fired case. This is done to get more accurate chamber pressure readings.
Quickload defaults to the lowest case capacity of 28.0 for the .223, and the Lake City case at 30.6 capacity is 5,000 psi lower in chamber pressure.
Bottom line, case capacity affects chamber pressure and not case weight. And the design of the throat/leade will affect chamber pressure.
Ballistic Tools
https://ballistictools.com/articles/5.56-vs-.223-myths-and-facts.php
As they say... It's easier to fool someone than it is to convince them that they have been fooled.
For the purposes of quickload which is a ball parking tool, water capacity is a common unit of measurement to help understand the area inside a case. Clearly, water capacity would differentiate between a 223 case volume and a 308 case volume for example.
But... The water capacity measurement is far too crude to be used to reliably evaluate differences between head stamps of the same cartridge. A variation of the smallest drop is greater than the difference between two cases, not to mention the weight variance created by air bubbles.
Even if the water capacity was a precise method, it does not serve to support an argument for or against the differences between 556 and 223, and it's completely meaningless for reloading purposes. Even factory produced ammo will have slight variations, and loads for each would have been developed accordingly. Factories do not arbitrarily put the same load in any case regardless of case weight. Factories also use strain gages to measure the amount of pressure to confirm they are within a stress range that is deemed safe, under any weather condition such as when the round and chamber is wet, like in the pouring rain. That in and of itself is grounds to mitigate the need for concern.
Yes, I would whole heartedly agree that it is not safe to jam a round into the chamber where the load is developed for a longer seating depth than the chamber can accommodate. This point applies primarily to the hand loader as is not in support of any claim that factory produced 223 or 556 deviate in jam length to a point that warrants interchangeability concern.
As for leade angles affecting chamber pressure... This is where a little knowledge is a dangerous thing. The point is valid, in a minor way, but assumes anyone involved in load development in factories is unaware of the point and would not have adjusted for the possibility.
You can regurgitate the legal disclaimer BS all you want. Many parrots have done the same before you came along.