kjohn, that looks exactly like some of the "squib" load cartridges we played with back in the day.
We were trying to Kaboom a Type 99 Japanese chambered in 7.7.
You could hardly give those rifles away back in the mid sixties.
There were all sorts of myths and rumors going around back then concerning the strength of Japanese firearms, which were debunked by PO Ackley and a couple of scientific institutions.
We had heard that squib loads could be made to detonate, rather than "control burn" so we thought we would test the theory on a cheap rifle known for being weak.
This Type 99 was one of the crudest, late war production pieces I had seen, and I saw a lot of them back then.
It was covered in rust, cracked stock, sewer pipe bore, parts missing, a classic JUNK grade firearm.
That was a long time ago and I don't remember the charge weighs of Super Vel that we used in surplus 7.7 Jap cases. We pulled the bullets and dumped the original powder, then put in a small charge of Super Vel powder and topped them off with .312 diameter 220 grain round nose FMJ, which were common back then.
The rifle came through the whole experiment looking just as good as when we started, however the cartridge cases, which were just over 20 years old at the time and about as factory fresh as was possible at the time, looked just like those in your pics when the charges started to get to the detonation point.
We never did get one to be much worse than those in your pics, because the powder charges got too small to ignite reliably.
Looking back, we were lucky to be using one of the strongest bolt action rifles built to that time.