Anything is possible, but rifling the muzzle end of the original barrel is likely a non-starter. Right off the bat, the groove depth would be greater than the bore diameter for the rest of the barrel (unless the barrel were reamed oversize), so the slug wouldn't get spun. Most bolt action shotguns have fairly meaty barrels, so there should be lots of steel for the counterboring and threading. You might want to shorten the barrel at the same time; this would leave the walls even thicker. The original muzzle will likely have been choked by swaging it into a cone, so cutting off a bit wouldn't be a bad idea anyway. All sorts of choke tubes are available in the various proprietary thread patterns. Brownells sells a sleeve which is soldered to the muzzle which accepts screwin choke tubes. Easy installation, cheaper than reaming and threading, I've done a couple, but the parts would now be covered by Commerce Dept. export controls. ER Shaw, in the US, of course, sells rifled 12ga barrel blanks for making up slug guns. Rebarrelling a bolt action shotgun isn't much different than rebarrelling a rifle. You could install a sidemount for a low powered scope, or a scout scope, or any pattern of rifle sights. Your basic idea of making up a dedicated bolt action slug gun is a good one.