First hot bluing attempt (update: more projects)

Well done ssapatch. One day I'll give the hot caustic bluing a go, but I was always a little reluctant. I choose to do express rust bluing. You only need one tank and decent set of gloves (more to prevent fingerprint oil on the parts and thermal protection).
 
Beautiful job! Never tried something like this but where would I be able to purchase these chemicals? And what's to cost on them?
 
Great write up, much appreciated! I've been considering setting up tanks and getting some solutions as well, good to hear another's experience it has it before diving into the deep end.


I was trying to find someone locally to just build me some tanks, and it was going to be surprisingly expensive per tank. So I just got annoyed and ordered from Brownells. And then the shipping hit me, so I ended up paying the same as I would have to get them made right here.

Also, I should have gotten at least 1 stainless tank for my final clean water boiling tank. The steel tank rusts, the rust dirties up the water and it's just more work to keep clean.

Beautiful job! Never tried something like this but where would I be able to purchase these chemicals? And what's to cost on them?

Sending you a PM.
 
This is the tank I use. Very well made. https://www.canadaammo.com/product/detail/stainless-steel-parkerizing-bluing-tank-with-drain/
I was trying to find someone locally to just build me some tanks, and it was going to be surprisingly expensive per tank. So I just got annoyed and ordered from Brownells. And then the shipping hit me, so I ended up paying the same as I would have to get them made right here.

Also, I should have gotten at least 1 stainless tank for my final clean water boiling tank. The steel tank rusts, the rust dirties up the water and it's just more work to keep clean.



Sending you a PM.
 
One possible source of potassium nitrate is a stump removal chemical like Spectracide. You can get it at Amazon.ca, or possibly Home Depot. Not so cheap though... $25 for a pound.

Spectracide Stump Remover

The on line MSDS sheets show it is 100% Potassium Nitrate.
 
I honestly thought I could use Tannerite as a source for nitrates. But it's oxidizer is made up of ammonium nitrate and ammonium perchlorate (according to Wikipedia), and I'm not sure how the perchlorate would react....or if it would have negative effects on the bluing.

It would be slightly cheaper (not much though) than the potassium nitrate, and more readily available.
 
Just remember stainless is no good for the actual bluing tank...

I blued for 50 years with all black iron tanks... never had a problem with the rinse tank being iron.
 
I believe you can add a third chemical - Sodium Nitrite to that recipe... 65%, 25%, 10%...

You have enough water in the mix when it boils nicely at about 285 and as the temperature rises add water... you shouldn't have to go above 300.

Maybe I missed it, but what does the addition of the third chemical do?
 
Just remember stainless is no good for the actual bluing tank...

I blued for 50 years with all black iron tanks... never had a problem with the rinse tank being iron.

Having a little rust in the rinse water never harmed or stained anything?
 
Having a little rust in the rinse water never harmed or stained anything?

Never a problem, when the parts came out of the boiling water I would blow excess water off, let them quickly dry and while too hot to handle I would cover them in oil and leave them over night.
 
I got curious, so I did a little test. Made a bunch of steel coupons to blue for different lengths of time. Time was split up into 5 minute intervals, starting at 5 minutes and ending at 60 minutes. I made 4 sets of 12 pieces, each polished differently. First was just wire brushed to get the mill scale off the steel. Second was polished with 120 grit. Third was polished to 320 grit. Fourth set was polished to 800 grit. All the polishing was done with just a random orbit air sander, and of course I didn't cut deep enough to remove all the tiny defects from the steel mill. But it gave me a good idea of the differences in polishing and time in the bluing solution.

I also realized how difficult it can be to get good pictures of freshly polished/blued metal. So much glare....

Here's the full set of 800 grit:

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And some more examples for your viewing pleasure.

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Pictures don't exactly show the whole story, it's something that's best seen with the naked eye.
 
I found about 30 minutes at a boiling 285+ worked well.

That's pretty much how I did the first gun, and it turned out quite nice.

I'm pretty sure the different types of steels account for differences in colour too. The rifle looks a fair bit darker, or more black, than any of these coupons.
 
Project #2, Ross 1905-R factory sporter. Check out this deep, shiny, purple-ish colour on the barrel! Caught me off guard when it turned out like that, but it's quite nice looking. Only problem is that it doesn't match the rest of the parts.

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