The only way canted rifle shooting works (as is done by some high end shooters) is to have offset mounts - the issue is to get the vertical line in the scope passing through the bore line - the rifle could be held at a 45 degree angle, so long as the scope mounts placed the vertical cross hair directly plumb above the bore.
And, to prove that, need a shooter with world class wind / mirage reading ability, unless there is an indoor many hundred yard range somewhere - Houston Warehouse, for example...
Thinking some more on that - if scope is mounted to be 1" to left of bore line, and "zero'd" on a target with group centered 1" to right of point of aim, it would continue to be 1" right until affected by atmosphere. Line of Sight though scope would be 1" to left of the Line of Bore.
I believe I have seen target rifles equipped with "swivelling" butt plates. It was my understanding this allowed the butt to mount to the shooter in a "canted" position, but the rifle and sights were being held square and plumb to the world.