The 25 Pounder Gun/Howitzer used "semi fixed" ammunition. That is, the projectile was loaded into the chamber and rammed until it was stopped by the rifling, by the Number Two Man on the gun crew. The brass case was then loaded into the chamber, and then it was ready to fire.
AMMUNITION and charged CARTRIDGE CASES were not joined together, but were separate from each other. The Ammunition Limber held 32 rounds of Ammunition, in trays for immediate use along with 32 fully charged brass cases. Each brass case held four powder charges in bags inside it, joined by a string, and had a formed composition cup on top to hold them in place, much like a shotgun wad. These were known, starting from the base (primer) end as Charge 1, Charge 2, Charge 3 and Super Charge. The cloth bags were different colours for each charge. Super Charge was only used for Anti-Tank use or emergencies as it was considered hard on the Gun for recoil. In actual use, the Firing Order would specify the Charge to use and the Gun Layer would use the appropriate setting on the sight drum. If, for example, Charge 2 was specified, one of the three men on the crew ( Numbers 4,5, or 6) would take the "Becket" (wad) out of the case, and break the connecting string off the Super Charge and Charge 3, leaving Charge 2 and Charge 1 inside the casing. He would discard the two powder bags taken off in a safe location to be burned later and insert the wad back into the case. Part of the composition of the wad contained an anti-fouling compound to ease wear and tear on the rifling of the bore. The case would then be loaded into the chamber of the gun behind the shell, and the gun was ready to fire.
Ammunition and loaded Cartridge Cases were NOT assembled and shipped in the same container. If, by some remote possibility that a Cartridge inside a steel ammunition box were to "explode", it would simply drive the WAD out the end, and not being restricted by a chamber, it would NOT be propelled FORWARD to cause damage as shown by the photograph, especially the "crimp" and compression of the case. It might split the mouth of the cartridge case, but it would have to be restricted in some way to compress the case.
Even thin rifle cartridges, when heated and "cooked off" simply pop the bullet out of the neck of a case, and do not have this type of compressed case damage.
If you look at the picture, the bottom bulge is not even from side to side from the collapse of the case walls, , and the mouth has a flare or enlargement. Given an educated thought, I would say that someone has put this case into a hydraulic press that had a top die for flaring pipe, (about 4 inch diameter), and applied pressure to compress the brass case.
Another "Urban Myth" busted.