I think the reason to select a release agent is to get something that the epoxy won't stick to, and that does so when very, very thin so the epoxy actually sets as very close fit to the metal. Tend to want to select epoxy that does not shrink when it hardens, for same reason. Some stuff will work as release as it does not let epoxy stick, but is "thick" or will stay "greasy" and harder to clean up afterwards or does not give a very snug "fit". Depends how fussy you want to be. I think often is to be able to use something already on hand in the house, rather than buy another thing that will dry out and become useless by the time the next job comes around... I am not familiar with the devcon release agent, but have used the "paint on" stuff that came with the Brownell's Acraglas kits - it dries like a plastic film that needs to be peeled off afterwards.