Much of the velocity is gained long after the peak pressure has been reached and is dropping off. Area under the curve is what really counts. Slower burning powders hold the pressure curve longer. Good barrels contain and seal the rapidly dropping pressure longer and more efficiently.
With the many variables it is possible to have higher velocity with less peak pressure. Hense fast barrels.
With the many variables it is possible to have higher velocity with less peak pressure. Hense fast barrels.