Changing the position of your eye relative to the muzzle is analogous to changing the rear site on a rifle. Raising your face on the comb will effectively raise the point of impact of your shot charge. If you "raise the muzzle end", you will raise the point of impact: is that what you want to do? If so, then raise your comb and corresponding eye position. If you want to approximate the change required, you can measure the distance from your eye to the muzzle when the gun is mounted and then simple geometry will tell you how much to raise or lower the comb to achieve the change in point of impact you wish to achieve. As a simple example, if the distance from your eye to the muzzle is 1 yard/36" and you want to raise your point of impact 12" at 40 yards/1440", then you have to raise the comb 36 x 12/1440 = 0.3 " at the point where your face meets the stock, which typically is 7 to 7.5 inches ahead of the butt plate.
Increasing the LOP can also have a very small effect because your face will be further back on the stock and therefore a bit lower if it is a typical butt stock with more drop at heel than comb but usually that change downward is only a very small fraction of an inch and not problematic with a field gun... potentially more so with a gun being used for long yardage handicap trap.
I hope that helps.