Start by zeroing the rifle at 100m. Bring a good supply of ammo with you when you do this as it may take awhile to get it right. The adjustments are fairly coarse, so move each knob in small increments while zeroing.
Begin by placing the elevation knob on the "1" or 100m setting, and the windage knob at "0". Shoot a group. I can't recall the actual amount the scope is offset to left of the bore, but I think it's around 1.25". Adjust the elevation and windage scope knobs accordingly to zero your group so that it hits point of aim for elevation, and approx. 1.25" to the right of point of aim for windage. After that is accomplished, we need to zero the scope knobs WITHOUT moving the reticle so that you can use the ranging feature of the scope. Provided its an actual U.S. G.I. scope, to zero your scope adjustment knobs for windage and elevation, you loosen the turret screw on each knob while holding the turret knob from turning and then lift up on the turret knob and turn to desired marking. So, if you zeroed at 100m, then you will want to turn the elevation knob back to the "1" or 100m setting, and the windage knob marking back to "0".
As for why the windage is not adjusted to be dead on the aiming point, it's because with the scope offset to the left, if you zeroed windage to point of aim, the rounds would start impacting to the left of your aiming point at any distance greater than what you zeroed at.
I hope this isn't too confusing...