762NATO brass while dimensionally the same 99.7% outside to .308Winchester, has a reduced internal capacity from thicker walls. Just take any once fired NATO case and a commercial .308Win, weight them empty on your loading scale and then filled to the mouth with water. By the differential you will see that the NATO round will hold around 2-3 grains less IIRC.
Years back when I extensively handloaded, if I got my hands on IvI NATO brass or Imperial .308Win brass, the internal capacity was lesser than Fed, Rem, Win etc etc. Apparently from by own deductions, as I have never seen it in print, when IvI loaded their commercial .308Win for the canadian market, they must have running the same brass they were loading for DND in 762NATO.
What this translated to in chamber pressure and resulting velocities with the same powder/primer charge worked up to max loads in a specific rifle,.. say in Remington cases,... and then applied to an Imperial case, I can't tell you. Now I wish I had done a velocity comparison over the chrony with my pet load of the day for sale, 165 Hornady Spire point over 46.5grs WW748/CCI250. A superbly accurate load in every rifle I fired it through, and even took a mediocre Browning Lever .308 from 2.5-3MOA down to 1.25". Nothing else could touch this load in this fussy rifle.
Wish I has some old loads lying around to try in the M-14. Maybe I'll have to set up the bench again! I know this powder burn rate/bullet combo may be a little hard on the M-14 op rod, I would have liked to see if it tightened up groups appreciably in my stock NorincoField M-14s.