If you are finding an old rimfire rifle hard to chamber - maybe get a good look at the inside of the chamber - a clear view of it - shine a flashlight in there - best with a bore scope, but your eye should be fine for this. Chamber walls should be shiny like a mirror - some will claim they should have very fine "cross hatch" but I have never seen that - no crud or crap stuck to walls. Depending what has been fired in it previously, the "shiny" should likely extend all the way to the start of the rifling. There is a thing about carbon deposits - can occur from using proper ammo and never cleaning it - can also occur by using smaller than "normal" rounds. Something to check, anyways.