Most power available in CO2 pistol/rifle

Sorry, ignored the C02 part, nevermind my advice. Umarex Hammer (50 cal) is probably up there with the most powerful pcp gun. But for general plinking, a pcp gun that you can tune to shoot sub supersonic will have great accuracy and decent power. I have a 22 cal pcp gun (Hatsan AT1022) that I have tuned to around 850 fps with 18 grain ammo and its very accurate, and shoots a great group at 50 yards. Not necessarily recommending Hatsan, but something similar in a pcp repeater is great fun and very useful. I charge mine from a scuba tank. Around 2300-2500 psi fill seems optimal from my testing with my gun.
 
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The Benjamin Discovery PCP is a dual powered (air or CO2) airgun that can use either air or CO2. A CO2 adapter with a paintball CO2 tank fills the rifle's reservoir. Velocities are higher when air is used, but the CO2 produces around 50 shots with velocities between 670 - 690 fps. This rifle is easily available in Canada and requires a PAL.

The Benjamin Challenger is another dual powered airgun.
 
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