I have no experience with the .455 Webly but can help a little with general black powder cartridge info.
You want to compress black powder at least a little. It often performs best (most consistently and cleanly) when highly compressed but that often takes a special compression die. In days gone past it was compressed into solid pellets and dropped into cases during loading. The black powder .303 British loads were done this way and the neck was formed after the cases where charged with powder.
Black powder can be measured by equivalent volumetric weight (with a scoop or brass measure) but this is a tad crude but usually works. I prefer to measure by weight same as any smokeless (but don't use a thrower designed for smokeless). You want a consistent mass (number of atoms/molecules) of propellant in the case. Since it's the atoms that react in the combustion, they are what matters, not how bulky they are.
If you seat to the same OAL there should be the same volume inside the case no matter how long the brass is. This is assuming they will still fit in the chamber seated to this length. There will be more of the bullet shank exposed. Don't forget to lube your bullets and that some black powder lubes can migrate and contaminate powder if left too long.
Pretty much all black powder loads use an over-powder-card of some kind. It's just a disk of cardboard or heavy paper between the powder and bullet. I bought some for my 45-70 loads (.460") from Track of the Wolf in the US. They likely have some suitable for your bullet diameter.
Black powder cartridge is really messy, a PitA to clean, but a lot of fun. Have you looked at possible Trail Boss loads for smokeless? I remember reading about those a little for .455 Webly. Trail Boss often gives higher pressures for a given velocity compared to most other smokeless powders so keep that in mind. Also never compress it.