For cartridge guns, slug the bore with a lead ball a small amount larger than the hole. Using an elongate piece of lead takes too much force for practical purposes. Also take a chamber cast and while Cerrosafe is what a gunsmith would usually use, you can get some pretty good measurements using parafin wax. Block the bore just ahead of the chamber and pour in melted wax. Let it cool and knock it out. You might try putting a piece of cotton string in the wax to keep the pieces together in case it cracks while removing.
Use a micrometer or good digital caliper to measure the base diameter, shoulder diameter, neck diameter and the length to the shoulder and total length then compare these to the published dimensions in Cartridges of the World. It is not uncommon for chambers to be a little oversize.
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