For your Rem, definitely bed that action and free float the barrel. Get rid of that barrel hump. If there is no squishing feeling when you tighten the action screws, pillar bedding is not that critical but not a bad idea. Of course, trigger lightening/tuning is never wasted money. Good Optics and mounts?
The best improvement you can make after this is handloading. I prefer to collet neck size my fired brass. 165gr SST and H4350Extreme lit by a CCI BR2 primer will give you superb accuracy.
There is little reason to believe your rifle cannot shoot MOA or better from a proper bench rest. However, if all you have is a 1.5 or 2MOA rifle, that is still plenty for normal hunting distances. From there you can work on your field position shooting and your max engagement distances.
ATR and I are going to differ on necessary accuracy. I believe that for deer, the max range you should shoot is 100% hit on a 10" target UNDER FIELD CONDITIONS. And I do mean 100% - no sighters, fouling shots or WHY. One shot, one hit rain/wind/snow/sun/standing/off a backpack/etc.
So, if you shoot from a bench set up in the field, your max range is going to be a lot further (assuming gun/load is up to the task) then shooting offhand. Heavy winds closer then dead still mornings, and so on.
The only way to know your max engagement ranges is to practise, practise, practise under the conditions and positions you intend to hunt. Even better if you can shoot in the areas you will hunt.
Knowing your limits, not necessarily what those limits are, is key to being a responsible hunter.
Jerry