To me, it looks like pieces of brass in the chamber. Did you take these pieces out and examine them? Shouldn't be hard to tell brass from what should be burned up pieces of corn cob or walnut. That is, unless you're tumbling in brass media, which would be new.
Also, from the look of the cartridge, there was no way that thing was fired in battery. When you fire in battery you don't see cartridges all twisted up like that. Over pressured cartridges will blow off the back end of the cartridge and leave the side walls, and throat of the cartridge stuck in the barrel. All the brass you get to see is the very bottom, and more often than not it'll be either long gone or stuck in the extractor (or what's left of it), the rest of the case stays in the barrel.
Also, look at the primer. That thing appears as round as it was when it was new. If this was an over pressure problem, the primer would typically be flat (there are rare exceptions).
Frankly, this shows some pretty glaring signs of an out of battery firing.
Do you full length resize your brass? Also was this brass fired in your gun prior to reloading, or is it 'from parts unknown'? Lastly, did you get the ka-boom after you pulled the trigger, or after the action cycled? I'm not familiar with the XCR, will the firing pin more forward when the action is open?