It's super easy. Just place your order on their site, and after you enter your Canadian address and complete the order, they email you directly (in a day or two) with an ITAR end user agreement you have to complete, sign, scan, and return. Obviously anything prohib in Canada (like unpinned high-cap mags) will be disallowed. The only unpleasant part is that they ship UPS to the border, then Canada Post takes it from there and assigns a new tracking number. I've ordered twice, and both times I was unable to get the Canada Post tracking number from Brownells.
FWIW Choate Machine also ships to Canada, for all your Ruger Mini needs.