Is your front sight at mechanical zero, meaning sitting in the middle of the sight base, and not appearing to lean left or right quite a bit?
If it sits in the middle,.. loosen you locking screw and drift your front sight to the right(opposite the direction you want your POI to move) a little to start, tighten up a check poi again with a couple rounds. It's better to get your intial zero with the front sight and leave the rear sitting in the middle.
If your front sight is already hard to the right or even hanging slightly off the front sight base, when viewed from the rear, you have I think, three options.
1. Get your rear sight operational and move it to the left 6 clicks to start, and live with the slight misalignment while obtaining a 100yd zero.
2. Remove your flash hider if sight appears to lean when viewed from rear, and see if the front sight base is cut properly so the sight base itself is true(perpendicular) down through top spline that engages the barrel slots. You will have to loosen the locking allen head screw first and use castlenut pliers to loosen the castlenut holding the flash hider to the barrel. Sometimes the older norks,( some 2009 and earlier) have the F/H plug welded to the barrel on it's underside, and this will add a bit more difficulty in it's removal. There is references to it in the above stickies, and I have seen YouTube vid's done by canadian M-14 owners showing how to remove a welded F/H.
3. If the F/H is cut correctly(mine isn't), and you want to use irons, a barrel re indexing may be in your future. If the Flash Hider looks really poorly cut in relation between the sight base and the corresponding splines, a used USGI flash hider may solve you problem. I have one in the mail as I type to try and correct my front sight issue.
Read all the stickies, and if you are set up to attend a Hungry clinic, all will be explained and if possible, made right for you there.
PS this post seems to duplicate some of whats typed previously, I took to long to type it as there was no replys when I looked.