FWIW I use 1/4 tsp (a 9mm case full) of Lemishine and 2 tbsp of Dawn in warm/hot water.
Everything goes in - dirt, sand, etc. I actually stopped using SS pins to save time separating them later. Brass is not shiny new like when using the pins but close enough.
I'm wondering if the excess amount of citric acid is causing your issue (with the nickle cases)?
Go to Value Village or somewhere similar and get a large stainless or even aluminum pot. Usually around $5. It needs to be large enough to hold at least a hundred standard length rifle cases or more, depending on how many you are cleaning most of the time.
Put the cases into the pot and fill it with water until there is a couple of centimeters above the level of the brass. Shake it up so all of the air is out of the cases.
Put the pot onto the stove top and bring to a rapid boil.
Add a quarter ounce of Lemshine or Sunlight detergent. I tried adding Dawn as well but it didn't make any difference. Let it boil for at least 10 minutes, with the lid on, then stir it all up with a wooden spoon. Boil for another 10 minutes with the lid on.
The brass will come out CLEAN. Not bright and shiny but clean.
Pour out the water, shake it all up or stir again and pour the water out again that was retained in some of the cases. I usually do this at least four times.
Here's the best part. The brass is HOT. You can leave it in the drained pot and come back to it a half hour later and it's all dry, ready to go through the reloading press.
You don't even have to rinse it.
I've cleaned up thousands of cases this way. The stainless pins are no longer used, nor is the tumbler.
Quick and simple. In under an hour, if your pot is large enough, you can clean a thousand 223 cases or a couple of thousand pistol cases. My pot will easily clean 500 standard size cartridge cases.
The boiling, combined with the Lemshine/Sunlight detergent will take of the baked on carbon but won't remove stains.
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