Don’t touch those .45 cal converters!!! You will regret it! Rob on Britishmuzzloaders has the best advice on powder and loading.
I like mine. You need to be careful not to load the cartridges to hot though or they will get stuck in the chamber and require a good sharp rap on a dowel with a mallet to loosen them up. I use a bit of lube on the outside of the adapter, which makes life much easier.
OP, One thing that always shows a good place to start with a BP load, I would use FFG in this situation, is to determine the depth you're going to seat your bullet and fill the case with enough powder so that it will be compressed when the bullet is fully seated.
You do not want an "air space" or loose powder charge when it comes to black powder loads. They will be inconsistent at best and at worst, can be very dangerous, turning your rifle into a pipe bomb under extreme conditions.
As far as bullet diameter goes, 577-450 Martini bores are notoriously inconsistent. Close, but nothing near that of today's barrels.
The original cartridges were paper patched so that these discrepancies could be dealt with effectively in the field.
You may want to try paper patching your bullets or slugging your bore and finding or ordering a custom mold which will cast bullets a few thou oversize to match.
When I'm loading BP cartridges, I use a very small charge of HS6 or something similar over the primer before topping up with BP.
The smokeless powder only needs to weigh 3-5 grains.
This really helps keep burn rates consistent and seems to leave less fouling behind in the bore, which means more shooting between cleaning.
My favorite bullet for the Martini, has a hollow base bullet, which is filled with automotive "BONDO" body filler to help it expand into the rifling and not leave any air space behind.
A good friend of mine, Jack Stead, out of Salmon ARM approaching the "centenarian mark" uses the same powder blend, but likes to use cards as wads under the bullet or fiber wads when he can find them. He was using a "waxed" fiber wad at one time, but didn't find they made any difference as long as his bullets had enough lubricant in the grooves.