I would expect that the percentage of OC in law enforcement pepper spray is significantly less than that of bear spray
Depends on the police force, but it's irrellevant. The higher concentration in bear spray is because it's used as a fogger - lower percentages actually penetrate faster because the capsicum is an oil. Police shove their spray right in a person's face as a rule - you need the higher concentrations when you're 'misting' and it thins out. it will in no way shape or form affect the target 'worse' or 'better'. That's why dog spray (pencil thin beam) is .05 and most bear sprays are .1. You would need much much much higher concentrations than either to have any serious damage to people.
A thug might weight from 150 to 300 pounds and a bear from 300 to 1500 pounds.
Again - irrelevant. You're affecting the mucous membranes, body weight has zero to do with it.
If you are correct however, and bear spray has no ability to asphyxiate the target, that makes its use a poor choice to stake your life on, so I hope that is not the case.
It is the case, and it's an excellent choice.
It's pretty clear you're not up on how the stuff works, which is understandable (most folks aren't). But it works very well in most cases. Which is why it's been such a very popular 'animal' deterrent for humans, bears and dogs. Cops wouldn't carry and use it so much if it 'didn't work'.
It does however have limitations. Some people will not have the same reaction and likely that's true of bears too. There is no way to 'test fire' it before you use it (once used, it will lose it's remaining pressure in a relatively short time. It has to be chucked) so there's always the possibility you've got a dud can. (very very rare - but possible.) The bear even if deterred stands a good chance of coming back, especially black bears. You have to be DAMN close to use it (i consider 20 feet damn close when you're talking bears). There is a tendancy to shoot too soon and use up most of the spray, leaving none if the bear comes back. People tend to point it like a pistol instead of firing from the hip, which is a bad mistake. Etc etc.
It's not perfect, but its effective and fills a role, alongside guns and bangers and electric fences etc etc. You need to understand how it works and where to use it, and then it's an effective tool (Same as all the rest.) It would likely be of less value if we could have pistols, but until we do, its definitely something to add to the 'toolkit' of bear defense systems. Use it where it makes sense, don't where it doesn't.