One of the difficulties faced by shooters is the challenge of knowing what results are typical and what are not. Anyone who's shot at 50 yards and has seen the range of group sizes often achieved understands that at longer distances group sizes can vary even more. One or a few groups can never meaningfully tell the tale of how well a rifle and ammo shoot.
With regard to ammo performance at increasing distances, if an ammo is very good at 100 yards -- in other words better than all the others being tested -- then it will be better than all those others at further distances. There's no such thing as an ammo that groups better as it goes further and further down range. No rounds have self-correcting mechanisms in them that adjust the trajectory for improvement.
To be sure, there are infrequent examples of .22LR ammo producing better MOA results at 100 meters than at 50 at the Lapua testing facilities. Such results, however, are unpredictable and can't be repeated on demand. And significantly, not all ammo from that particular lot will behave the same way -- that is, do better at 100 than at 50. Such anomalies are caused by an offset center of gravity in individual bullets. These irregularities in the ammo can't be anticipated.