I contacted Petrosoli in Italy and they responded very quickly. Say the Barnes Pioneer is below the 29000 psi and is perfectly fine in their rolling blocks. actual response
Dear Mr. Bruce,
In Europe we follow the rules set by the C.I.P (similar to SAAMI) which forecasts the limit pressure of 31908 P.S.I. for the .45-70 caliber.
The ammo you chose is perfectly within those parameters.